Stockpiles of discarded automobile tires might soon shrink with the advent of a process designed to recover A one-step technique recovers polymeric oils by breaking the sulfur-to-sulfur bonds responsible for the durability of modern tires. Source: S. Zheng et al.A one-step technique recovers polymeric oils by breaking the sulfur-to-sulfur bonds responsible for the durability of modern tires. Source: S. Zheng et al.petroleum-based polymers from these materials for reuse.

A one-step technique developed at Canada’s McMaster University recovers polymeric oils by breaking the sulfur-to-sulfur bonds responsible for the durability of modern tires. Sulfur crosslinks were degraded by use of tris(pentafluorophenyl)borane, a compound with strong Lewis acidity commonly used in catalytic applications. The method effectively reduced sulfur-sulfur bonds in samples of tire crumb, solid tires and bicycle inner tubes, yielding organic polymers.

The recovered polymeric oils can be filtered and upgraded to form new elastomers, as was demonstrated by synthesizing a new automotive tire for a child’s toy by use of oxidative crosslinking reactions.

The technique described in Green Chemistry is currently far too expensive to be scaled up for industrial applications, but the researchers hope to render the recycling technology more cost-effective with a view to wider applications.

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