About 300 million tons of the 380 million tons of plastics produced worldwide each year end up in landfills or the environment. An efficient route based on catalytic hydrogenolysis has been advanced for recovering and upcycling single-use polyethylene (PE) into liquid hydrocarbons to reduce this waste burden.

The process detailed in ACS Central Science uses a catalyst composed of platinum nanoparticles Electron micrograph of platinum nanoparticles deposited onto a perovskite nanocube. Source: Argonne National LaboratoryElectron micrograph of platinum nanoparticles deposited onto a perovskite nanocube. Source: Argonne National Laboratorydeposited onto perovskite nanocubes to break the carbon bonds in high molecular weight PE materials via selective hydrogenolysis. Tests confirmed that sequential hydrogenolysis occurs and results in selective formation of narrower high-quality liquid products, which can be used as ingredients in the manufacture of motor oils, waxes and other products.

Catalytic hydrogenolysis of PE was demonstrated with a single-use, commercial-grade plastic bag and other materials as feedstock. The method also generated less waste and toxic byproducts than other plastic recycling technologies.

Researchers from Iowa State University, Argonne National Laboratory, U.S. Department of Energy Ames Laboratory, Cornell University, University of South Carolina, University of California Santa Barbara and Northwestern University contributed to this development.

To contact the author of this article, email shimmelstein@globalspec.com