A team of scientists from Aalto University and the University of Bayreuth has developed a flexible, self-healing hydrogel that promises to open up possibilities in wound healing, soft robotics, artificial skin and drug delivery applications.

The researchers explained that to accomplish such features in typically rigid hydrogel, they used ultra-thin clay nanosheets, which created a dense entangled network of polymers that strengthened hydrogels and prevented them from being too soft. This also, reportedly, increased the gel’s ability to self-repair.

Illustration of hydrogels in a mobius-ring formed through self-healing. Source: Margot Lepetit/Aalto UniversityIllustration of hydrogels in a mobius-ring formed through self-healing. Source: Margot Lepetit/Aalto University

The team noted that they mixed a powder of monomers with water containing the nanosheets and that mixture was subsequently placed under a UV lamp wherein the UV radiation from the lamp caused the individual molecules to bind together so that everything became an elastic solid, otherwise known as a gel.

“Entanglement means that the thin polymer layers start to twist around each other like tiny wool yarns, but in a random order,” added the researchers. “When the polymers are fully entangled, they are indistinguishable from each other. They are very dynamic and mobile at the molecular level, and when you cut them, they start to intertwine again.”

As such, the team explained that the hydrogel’s healing process was expedited, reportedly repairing 80% to 90% of itself within the first four hours of being cut, and they restored themselves entirely after twenty-four hours. The team also noted that the hydrogel is comprised of 10,000 layers of nanosheets in a sample that is 1 mm thick, which enables it to achieve stiffness similar to that of human skin while also allowing it to stretch.

The study, “Silk-inspired in situ web spinning for situated robots,” appears in the journal Nature Materials.

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